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Photophysical and Photochemical Studies on a Tetraphenylethene Derivative
Pages: 463-470
Year: Issue:  5
Journal: Imaging Science and Photochemistry

Keyword:  tetraphenylethenephotoreactionoxidationaggregation induced emission;
Abstract: 设计合成了一个四苯基乙烯衍生物Model-TPE,该化合物具有典型的聚集诱导发光(AIE)特性.1HNMR、质谱以及高效液相色谱研究表明,有氧条件下Model-TPE经紫外光照射发生关环反应,生成二苯基取代菲衍生物,取代和未取代苯环侧关环反应得到异构体产物,提出了光氧化关环反应机理.本工作对TPE衍生物在发光及传感领域的应用有一定的指导意义.
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