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Intramolecular Photocyclodehydrogenation of Hexa (4-substituted-phenyl) benzene
Author(s): 
Pages: 484-489
Year: Issue:  5
Journal: Imaging Science and Photochemistry

Keyword:  hexa(4-substituted phenyl) benzenephotocyclodehydrogenation reactionoxidation;
Abstract: 研究了六苯基苯衍生物的分子内光化学关环脱氢反应,与热化学关环脱氢反应不同,光化学关环脱氢反应只生成关一个环的产物.光化学关环脱氢反应过程中,氧化剂种类、用量以及溶剂对关环脱氢产物的产率具有显著影响,在正己烷溶剂中,以单质碘为氧化剂进行光化学关环脱氢反应,关环产物产率可达91%.
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