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Solid-state Asymmetric Photochemistry of Bicyclo [3.1.0]hexyl Ketone Carbonyl Derivatives
Pages: 455-462
Year: Issue:  5
Journal: Imaging Science and Photochemistry

Keyword:  asymmetric synthesischiral auxiliarysolid state photochemistryNorrish Ⅱ;
Abstract: 由二环庚二烯为起始原料合成二环己烷酮类衍生物,以手性胺作为手性辅助剂进行固相不对称光化学反应研究,探讨了反应时间和反应温度对光化学裂解产率和对映选择性的影响,ee值最高达到75%.
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